Bitumen Emulsions

Bitumen Emulsions have being developed and exponentially increased sinned they were created in 1900. Estimated presently at 20% of the global bitumen use, bitumen emulsions are basically an O/W – Oil on Water solution – A dispersion of bitumen particles on water, stabilized with the addiction of surfactants – Surface active agents – or most commonly known as emulsifiers, that will permit the bitumen to de diluted in water. They are primarily used for tack coats for use in between hot mix asphalt layers and prime coats for thin hot mix surfacing layers or a chip seal pavements.

Bitumen emulsions are divided into three categories:

  • Anionic with negatively charged globules
  • Cationic with positively charged globules
  • Non-ionic with neutral globules.


The main grades for bitumen emulsions are classified as follows:
Anionic Emulsion CodeCationic Emulsion CodeSetting Type
ARS CRS Rapid Setting
AMS CMS Medium Setting
ASS CSS Slow Setting

Bitumen Emulsion is an area where technological progress is still being made to meet the requirements of pavement engineering. Anionic emulsions were first developed. They are currently less favored than the cationic emulsions, as cationic emulsions coat the aggregates more efficiently due to their positive load and have therefore better adhesion properties. Cationic Emulsion is both more favored and more widely used.

Emulsified Bitumen usually consists of bitumen droplets suspended in water. This dispersion under normal circumstances would not take place, since everyone knows that oil and water don’t mix, but if an emulsifying agent is added to the water the asphalt will remain dispersed. Most emulsion are used for surface treatments. Emulsions enable much lower application temperatures to be used. Application temperatures range from 45°C to 70°C. This is much lower than the 150 to 190°C used for hot mix asphalt cements. The lower application temperatures will not damage the asphalt and are much safer for field personnel.

In the production of bitumen emulsion, water is treated with an emulsifying agent and other chemicals and is pumped to a colloid mill along with bitumen. The colloid mill breaks the bitumen up into tiny droplets. The emulsifying agent migrates to the asphalt-water interface and keeps the droplets from coalescing. The emulsion is then pumped to a storage tank.

Bitumen emulsions are complicated and good chemistry is required to reach target desired emulsion properties. Variables in emulsion production include the base bitumen and the type and amount of emulsifying agent. There are two basic classifications of emulsions globally usually used, anionic bitumen emulsions and cationic bitumen emulsions. The type (chemistry) of the emulsifying agent used, determines the designation. Emulsifying agents are the chemicals used to stabilize the emulsion and keep the “billions and billions” of bitumen drops separated from one another. These compounds are large organic molecules that have two distinct parts to them. These parts are called the “head” and “tail.” The “head” portion consists of a group of atoms that chemically have positive and negative charge areas. These two charged areas give rise to the head being called polar (as in poles of a magnet). Because of this polarity, and the nature of some of the atoms in this polar head, the head is soluble in water. The tail consists of a long chain organic group that is not soluble in water, but is soluble in other organic materials like oils (bitumen). Thus, an emulsifying agent is one molecule with both water-soluble and oil soluble portions. This unique characteristic gives the chemical its emulsifying ability.

Anionic Emulsions

The term anionic is derived from the migration of particles of bitumen under an electric field. The droplets migrate toward the anode (positive electrode), and hence the emulsion is called anionic. In an anionic emulsion, there are “billions and billions” of bitumen droplets with emulsifying agent at the water bitumen interface. The tail portion of the emulsifying agent aligns itself in the bitumen while the positive portion of the head floats around in the water leaving the rest of the head negatively charged and at the surface of the droplet. This imparts a negative charge to all the droplets. Since negatives repel each other, all the droplets repel each other and remain as distinct bitumen drops in suspension. A typical anionic emulsifying agent is shown below along with a diagram showing the orientation of the agent at the bitumen-water interface and the negative charge imparted to each drop.

Typical Anionic Emulsifying Agent
Typical Anionic Emulsifying Agent
Cationic Emulsions

The term cationic is derived from the migration of particles of bitumen under an electric field also. The droplets migrate toward the cathode (negative electrode), and hence the emulsion is called cationic. The cationic emulsifying agent functions similarly to the anionic; the negative portion of the head floats around in the water leaving a positively charged head. This imparts a positive charge to all the droplets. Since positives repel each other, all the droplets repel each other and remain as distinct bitumen drops in suspension. A typical cationic emulsifying agent is shown below along with a diagram showing the orientation of the agent at the bitumen-water interface and the positive charge imparted to each drop.

Typical Cationic Emulsifying Agent
Typical-Cationic-Emulsifying-Agent
Breaking Characteristics of Emulsions

Emulsions exist for ease of application. After application the water to should evaporate and leave the asphalt cement. In a surface treatment, after emulsion and aggregate have been applied to the road surface, the emulsion should “break” leaving the asphalt cement holding the aggregate. At that point traffic may be allowed on the surface without loss of aggregate. The type of emulsion used has a large effect on the speed of the “break” of an emulsion.
Almost all surfaces have a net negative charge. The strength or intensity of this negative charge may be different from material to material. Because of this phenomenon, anionic and cationic emulsions break in different ways.
In an application of anionic emulsion, negatively charged drops of asphalt are applied to a negatively charged surface. All components repel each other. The only way the emulsion can break is through the loss of water by evaporation. As more and more water is lost through evaporation, the particles are forced closer and closer together until they can no longer be separated by a film of water. At this point droplets coalesce into larger and larger drops and ultimately a sheet of asphalt on the road. A depiction of the application is shown below:


anionic-emulsion-application

In an application of cationic emulsion, we are applying positively charged drops of bitumen to a negatively charged surface. The bitumen drops are immediately attracted to the surface and begin to break. The emulsion also loses water by evaporation. Thus the cationic emulsion has two breaking mechanisms at work and will break faster than a corresponding anionic emulsion. A depiction of the application is shown below:

cationic-emulsion-application

The object of a surface treatment is to seal the road from moisture intrusion and provide a new skid resistant surface, but be open to traffic as soon as possible and retain aggregate. Due to the chemistry of emulsions, they may react differently in specific weather and application conditions. If you have problems in any of these areas, the problem could be because of the weather, aggregate condition or emulsion used.

In bitumen emulsions the basic bitumen has also been diluted in order to facilitate application. Hot bitumen, water and emulsifier are processed in a high-speed colloid mill that disperses the bitumen in the water. The emulsifier produces a system in which fine droplets of bitumen, of between 30% and 80% of the volume, are held in suspension. If they separate in storage, the emulsion can easily be restored by agitation.

Bitumen emulsions have a low viscosity and can be workable at ambient temperatures, which makes them ideal for use in road pavements and surfacing. This application requires controlled breaking and setting. The emulsion must not break before they are laid on the road surface but, once in place, they should break quickly so that the road can be in service again without delay.

Bitumina supplies and provides transfer of technology for production of both Anionic & Cationic Bitumen Emulsions in correspondence to ASTM D977-12 and EN 13808-2005. For any inquiries, please contact our sales team on info@bitumina.co.uk

TACK COAT:

What is tack coat?

Tack coat (also known as bond coat) is a light application of asphalt emulsion between hot mix asphalt layers designed to create a strong adhesive bond without slippage. Heavier applications may be used under porous layers or around patches where it also functions as a seal coat.

Why use tack coat?

Without tack coat the asphalt layers in a road way may separate which reduces the structural integrity of the road and may also allow water to penetrate the structure

What type of emulsion should be used for tack coats?

The type of emulsion used for tack coats varies from country to country. Normal practice in the USA is to use a slow-setting emulsion that is diluted with water before application. In many European countries cationic rapid setting or specially designated low viscosity medium setting emulsions are used, which are applied undiluted.

Prime Coat:

Why use prime coat?

Prime coats protect the integrity of the granular base during construction and help reduce dust. In the case of a base which is to be covered with a thin hot mix layer or a chip seal for a low volume roadway, priming ensures a good bond between the seal and the underlying surface which otherwise would have a tendency to delaminate.

Why use asphalt emulsion prime?

Compared to cut back asphalt primes, emulsion primes are environmentally friendlier.

What type of emulsion is most suitable for emulsion prime?

Slow-setting grades of asphalt emulsions (diluted with water before application) are suitable. With dense granular bases, or stabilized bases the surface may need to be broken up by scarifying before application, to ensure good penetration.